Product ID:2006 LACTOL SPIRITS
MSDS Date:11/28/1995
FSC:6810
NIIN:00-082-1718
Status Code:A
MSDS Number: CJDDJ

UNION OIL COMPANY OF CALIFORNIA

1701 GOLF ROAD,SUITE 1-1101
ROLLING MEADOWS, IL 60008-4295
US

Emergency Phone: 800-967-7601

Info Phone: 800-967-7601

Cage: TO018

UNION OIL COMPANY OF CALIFORNIA

ROLLING MEADOWS, IL 60008-4295 US

Telephone: 800-967-7601

Cage: TO018

SOLVENT NAPHTHA, LIGHT ALIPHATIC

CAS: 64742-89-8

METHYLCYCLOHEXANE

CAS: 108-87-2

RTECS: GV6125000

OSHA PEL 2000 MG/M3;500 PPM

ACGIH TLV: 1610 MG/M3;400 PPM

N-HEPTANE

CAS: 142-82-5

RTECS: MI7700000

OSHA PEL 2000 MG/M3;500 PPM

ACGIH TLV: 1640 MG/M3;400 PPM

TOLUENE

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL see Table Z-2

ACGIH TLV: 188 MG/M3;50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CYCLOHEXANE

CAS: 110-82-7

RTECS: GU6300000

OSHA PEL 1050 MG/M3;300 PPM

ACGIH TLV: 1030 MG/M3;300 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE

CAS: 71-43-2

RTECS: CY1400000

OSHA PEL see 1910.1028

ACGIH TLV: 32 MG/M3;10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

OTHER C6-C8 PARAFFINS AND CYCLOPARAFFINS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and
Chronic:EYE-IRRIT.STINGING,WATERING,REDNESS,SWELLING.SKIN-IRRIT.RED
,BURN,DRY,CRACK,SKIN DMG.LOW DEGREE OF HAZ BY SKIN
ABSORPTION.INHAL-LOW-MOD DEGREE OF TOXICITY.INGEST-LOW-MOD DEGREE
OF TOXICITY.ASPIRATION H AZ-CAN ENTER LUNGS,CAUSE LUNG
INFLAMM/DMG.TARORG-POT HAZ TO CNS,KID,LIV,& SENSE OF HEARING.
Explanation of Carcinogenicity:INADEQUATE EVIDENCE AVAILABLE TO EVALUTE
THE CANCER HAZ OF THIS MATL.MATL HAS NOT BEEN ID AS CARC BY
NTP/IARC/OSHA.
Effects of Overexposure:EFFECTS OF OVEREXPO MAY INCLUDE IRRIT OF
NOSE&THROAT,IRRIT OF DIGESTIVE TRACT,NAU, VOMIT, DIARR,SIGNS OF
NERV SYST DEPRESS(E.G.HEAD,DROWS,DIZZ,LOSS OF
COORDINATION,FTG).REPORT HAVE ASSOC REP/RPOL OCCU P OVEREXPO TO
SOLVTS W/PERM BRAIN&CNS DMG(SOLVT/PAINTERS SYNDROME).INTENTIONAL
MISUSE BY DELIBERATELY CONC/INHAL MATL MAY BE HARMFUL/FATAL.
Medical Cond Aggravated by Exposure:MAY INCLUDE SKIN
DISORDERS,RESP(ASTHMA- LIKE)DISORDER,KIDNEY&LIVER DISORDERS.EXPO TO
HI CONC OF MATL MAY CAUSE IRREG HEARTBEATS (ARRHYTHMIAS).PERSONS
W/PRE-EXISTING HEART DISORDERS MAY BE MORE SUSCEPT

First Aid:EYE-MOVE TO FRESH AIR.IRRIT/RED DVLP FLUSH W/H2O.GET MED
ATTN.EYELIDS APART,FLUSH W/HWO @LEAST 15MINS.SKIN-REMOVE CONTAM
CLOTH.FLUSH W/LG AMTS OF H2O.SKIN DMG APPLY CLEAN DRESS,GET MED
ATTN.NOT DMG CL EANSE WELL W/MILD SOAP/H2O.IRRIT/RED DVLP GET MED
ATTN.INHAL- MOVE TO FRESH AIR.SYMPT PERSIST GET IMMED MED ATTN.NOT
BREATH IMMED GIVE ART RESP;DIFFI BREATH GIVE OXY.GET IMMED MED
ATTN.INGEST-GET EMER G MED ATTN.CONSC/ALERT INDUCE VOMIT.DR: EXPO
HI CONC MATL ASSOC W/CARDIAC ARRHY.EPINEPHRINE/OTHER MAY INITIATE
CARDIAC ARRHY IN THOSE EXPO TO MATL.OBSERV FOR CARDIAC ARRHY

Flash Point Method:TCC
Flash Point:=-6.7C, 20.F
Autoignition Temp:=304.4C, 580.F
Lower Limits:1
Upper Limits:7
Extinguishing Media:RECOMMEND DRY CHEM/CO2/HALON/FOAM.H2O MAY BE INEFF
FOR EXT UNLESS UNDER FAVOR CONDITONS BY EXPER FIREFIGHTER. HALON
DECOMPO-TOX MATL.CO2 DISPL OXY.USE CAUT W/HALON/CO2 IN CONF SPACE.
Fire Fighting Procedures:EMERG RESPONDER SHOULD WEAR BUNKER GEAR/SCBA
FOR FIRE BEYOND INCIPIENT STAGE. ADDN WEAR OTH APPRO PROT EQPMT AS
CONDITIONS WARRANT.ISOLATE.STOP SPILL/LEAK W/O RISK. MOVE UNDMG
CNTNR FRM AREA W/O RISK. H2OSPRAY-MIN/DISP VAP.COOL EXPO EPQMT
W/H2O W/O RISK. AVOID SPREAD BURNING LIQ W/ H2O.H2OSPRAY COOL/PROT
EXPO MATL/STRUC
Unusual Fire/Explosion Hazard:FLAMM,IGN BY HEAT,SPARK,FLAME,OTH IGN
SOURCE.VAP TRAVEL CONSIDERABLE DISTANCE TO IGN SOURCE-IGN
&FLASHBACK,EXPLODE.CREATE VAP/AIR EXPLO HAZ INDR/OUTDR/SEWER.CNTNR
NOT PROPERLY COOLED CAN EXPLO IN HEAT OF FIRE.

Spill Release Procedures:FLAMM.KEEP ALL IGN SOURCES AWAY.USE
EXPLO-PROOF EQPMT.STAY UPWIND/AWAY.ISOLATE.STOP W/O RISK.WEAR
APPROP PPE AS CONDITIONS WARRANT.PREVENT SPILL ENTER SEWER/STORM
DRAIN/ OTHER.DIKE.USE FOAM TO MIN VAP .USE APPROP ABSORBENT.NOTIFY
AUTHORITIES/APPROP AGENCIES. NOTIFY NRC 800-424-8802 IF ENTER
WATERWAY/EXCESS EPA RQ.

Handling and Storage Precautions:OPN CNTNR SLOWLY.BOND/GROUND EQPMT
WHEN TRANSF FRM VESSEL TO VESSEL.ACCUMUL STATIC CHARGE BY
FLOW/AGITATION.VAP IGN BY STATIC DISCHAR.RECOMMEND EXPLO PROOF
EQPMT. DONT ENTER CONF SPACE(TANKS,PITS)W/O PROPER ENTERY
PROCEDURE(ASTM D4276,29CFR1910.146). ADVISE USE RESP PROT WHEN CONC
EXCEED EXPO LIMIT.
Other Precautions:EMPTY CNTNR RETAIN RESIDUE-DANGER.DONT
PRESS,CUT,WELD,BRAZE,ETC,EXPO TO HEAT-CAN CAUSE INJURY/DEATH.BEF
WORK ON/IN TANK WHICH HAS/HAD MATL SEE OSHA REGS/ANSI Z49.1/OTHER
REFS PERTAIN TO CLEAN/REPAIR/W ELD/CONTEMPLAT OPS. KEEP TIGHTLY
CLSD.USE/STORE IN COOL DRY WELL VENTI AREA AWAY FRM HEAT.PROT FRM P
HYS DMG.

Respiratory Protection:SUE OF RESP PROT ADVISED WHEN CNC EXPECTED TO
EXCEED ESTABLISHED EXPO LIMITS.DEPENDING ON AIRBORNE CONC USE RESP
W/APPROP CARTRIDGES(NIOSH APPROV IF AVIA) OR SUPPLIED-AIR EQPMT.
Ventilation:CURRENT VENTI PRACT NOT ADEQUATE TO MAINTAIN AIRBORNE CONC
BEL EXPO LMTS ADDN VENTI/EXHAU SYS MAY BE REQUIRED.EXPLO MIX
PRESENT ELECTR SYS SAF FOR SUCH LOCATION
Protective Gloves:GLOVES IMPERMEABLE TO SPECIFIC MATL HNDL IS ADVISED.
Eye Protection:APPROV EYE PROTECTION TO SAFEGUARD AGAINST
CONTACT/IRRIT/INJURY RECOMMENDED.
Other Protective Equipment:EYEWASH&QUICK-DRENCH SHOWER FACILITIES
SHOULD BE AVAI IN WORKAREA.THOROUGHLY CLEAN SHOES & WASH CONTAM
CLOTH BEFORE REUSE.RECOMMEND THAT IMPERVIOUS CLOTH BE WORN.
Work Hygienic Practices:WASH WELL AFT HNDL.DONT WEAR CONTAM
CLOTH/SHOES.USE GOOD PERSONAL HYG PRAC.AVOID EYE/SKIN/CLOTH
CONTACT.DONT TASTE/INGEST.
Supplemental Safety and Health

HCC:F2
Vapor Pres:25
Vapor Density:3.4
Volatile Org Content %:100
Spec Gravity:0.745 @60F
pH:NA
Viscosity:0.68 CST
Evaporation Rate & Reference:3.9 (NBUAC=1)
Solubility in Water:0.02
Appearance and Odor:WATER-WHITE COLOR, LIQUID, LIGHT HYDROCARBON ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID ALL POSSIBLE SOURCES OF IGNITON.AVOID CONTACT WITH STRONG
OXIDIZING AGENTS AND REDUCING AGENTS.
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITONS OF STORAGE
AND HANDLING.FLAMMABLE LIQUID AND VAPOR.VAPOR CAN CAUSE FLASH FIRE.
Hazardous Decomposition Products:COMBUSTION CAN YIELD CARBON DIOXIDE
AND CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR

Waste Disposal Methods:RCRA HAZ WASTE IF DISCARD IN PRODUCED FORM.EPA
D001,D018.HNDL EMPTY CNTNR W/CARE-RESIDUE- DRAIN COMPETELY,PROP
BUNGED,PROMP RETURN TO SUPPLIER/SHIPP TO DR RECONDITONER.DISPO ALL
CNTNR IN ENVIRO SAFE M ANNER,IAW GOVT REGS.RINSATE MAY BE
CONSIDERED RCRA HAZ WASTE,DISPO W/CARE.STATE/LOC REQMT MORE RESTR
ICTIVE/DIFFER FRM FED.CONSULT STATE/LOC REGS

Toxicological Information:TOLUENE:TARORG-INTENTIONAL MISUSE BY
DELIBERATE INHAL OF HI CONC OF TOLUENE HAS BEEN SHOWN TO CAUSE
LIV/KID/CNS DMG INCLUDE HEARING LOSS & VISUAL DISTURB.SUBCHRONIC &
CHRONIC INHAL STUDIES W/TOLUENE P ROD KID/LIV DMG,HEAR LOSS,CNS
DMG(BRAIN DMG)IN LAB ANIMALS.DEVLPMTAL:EXPO TO TOLUENE DURING PREG
HAS DEMO LMTD EVIDENCE OF DVLPMENTAL TOX IN LAB ANIMALS.EFFECTS
SEEN INCLUDE DECR FETAL BODY WT & INCR SKELETAL VARIATIONS IN BOTH
INHAL & ORAL STUDIES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:PER MSDS:DOT PROPER SHIPPING-PETROLEUM
DISTILLATES,N.O.S.(NAPHTHA SOLVENT),3,UN1268,PKG II.

SARA Title III Information:MATL CONTAINS FOLLOWING CHEMS SUBJ TO
REPORTING REQMTS OF SARA 313/40CFR372: TOLUENE CAS#108-88-3 10-18%
& CYCLOHEXANE CASE#110-82-7 1-3%.
Federal Regulatory Information:EPA(CERCLA)REPORTABLE QUANTITIY:RQ#1
TOLUENE 1000 LB EQUAL TO 5556LB(896GAL)OF THIS MATL. RQ#2
CYCLOHEXANE 1000LB EQUAL TO 33333LB(5276GAL)OF THIS MATL.
State Regulatory Information:WARNING:MATL CONTAINS FOLLOWING CHEMS
WHICH ARE KNOWN TO STATE OF CA TO CAUES CANC, BIRTH DEFECTS OR
OTHER REPRODUCTIVE HARM & ARE SUBJ TO REQMTS OF CA PROP 65(CA
HEALTH & SAF CODE SEC 25249.5):BENZEN E CANC,TOLUENE DEVELOPMENT
TOXICANT.